Experimental Evidence of Phosphine Oxide Generation in Solution and Trapping by Ruthenium Complexes | Zendy

Yakhvarov Dmitry | Zendy; Caporali Maria | Zendy; Gonsalvi Luca | Zendy; Latypov Shamil | Zendy; Mirabello Vincenzo | Zendy; Rizvanov Ildar | Zendy; Sinyashin Oleg | Zendy; Stoppioni Piero | Zendy; Peruzzini Maurizio | Zendy

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Experimental Evidence of Phosphine Oxide Generation in Solution and Trapping by Ruthenium Complexes

Author(s) -

Yakhvarov Dmitry,

Caporali Maria,

Gonsalvi Luca,

Latypov Shamil,

Mirabello Vincenzo,

Rizvanov Ildar,

Sinyashin Oleg,

Stoppioni Piero,

Peruzzini Maurizio

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201100822

Subject(s) - phosphine , ruthenium , phosphine oxide , chemistry , oxide , tautomer , ligand (biochemistry) , phosphorus , combinatorial chemistry , photochemistry , organic chemistry , catalysis , biochemistry , receptor

Phosphine oxide (H 3 PO), the first defined compound of phosphorus in the oxidation state −1, was obtained in solution by electrochemical methods starting from white phosphorus (see picture). H 3 PO was characterized by NMR solution spectroscopy as a free molecule and isolated as a ligand in ruthenium(II) complexes following tautomerization to phosphinous acid, H 2 P(OH).

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