Porous and Dense Magnesium Borohydride Frameworks: Synthesis, Stability, and Reversible Absorption of Guest Species | Zendy

Filinchuk Yaroslav | Zendy; Richter Bo | Zendy; Jensen Torben R. | Zendy; Dmitriev Vladimir | Zendy; Chernyshov Dmitry | Zendy; Hagemann Hans | Zendy

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Porous and Dense Magnesium Borohydride Frameworks: Synthesis, Stability, and Reversible Absorption of Guest Species

Author(s) -

Filinchuk Yaroslav,

Richter Bo,

Jensen Torben R.,

Dmitriev Vladimir,

Chernyshov Dmitry,

Hagemann Hans

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201100675

Subject(s) - borohydride , magnesium , absorption (acoustics) , chemistry , inorganic chemistry , combinatorial chemistry , photochemistry , organic chemistry , materials science , catalysis , composite material

Highly occupied : A highly porous form of Mg(BH 4 ) 2 (see picture; Mg green, BH 4 blue, unit cells shown in red) reversibly absorbs H 2 , N 2 , and CH 2 Cl 2 . At high pressures, this material transforms into an interpenetrated framework that has 79 % higher density than the other polymorphs. Mg(BH 4 ) 2 can act as a coordination polymer that has many similarities to metal–organic frameworks.

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