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Stable N‐Heterocyclic Carbene Complexes of Hypermetallyl Germanium(II) and Tin(II) Compounds
Author(s) -
Katir Nadia,
Matioszek Dimitri,
Ladeira Sonia,
Escudié Jean,
Castel Annie
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201100634
Subject(s) - tin , germanium , carbene , germanium compounds , reagent , chemistry , magnesium , combinatorial chemistry , organic chemistry , catalysis , silicon
A selective route : Hypermetallyl germanium(II) and tin(II) compounds (see scheme) were prepared using dimetallyl magnesium reagents and were fully characterized. These derivatives, which contain good leaving substituents, might be suitable candidates for the preparation of nanomaterial alloys.