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A Biologically Relevant Co 1+ ⋅⋅⋅H Bond: Possible Implications in the Protein‐Induced Redox Tuning of Co 2+ /Co 1+ Reduction
Author(s) -
Kumar Manoj,
Kozlowski Pawel M.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201100469
Subject(s) - redox , variety (cybernetics) , event (particle physics) , chemistry , computer science , process (computing) , combinatorial chemistry , physics , organic chemistry , operating system , quantum mechanics , artificial intelligence
Reduced circumstances : A hydrogen bond induced by the Co + ion has been identified theoretically (see picture). It plays a vital role in explaining the mechanistic base of protein‐induced tuning of the Co 2+ /Co + redox process, a common catalytic event in a wide variety of methyltransferases and adenosyltransferases.