Premium
Covalently Linked Porphyrin–La@C 82 Hybrids: Structural Elucidation and Investigation of Intramolecular Interactions
Author(s) -
Feng Lai,
Slanina Zdenek,
Sato Satoru,
Yoza Kenji,
Tsuchiya Takahiro,
Mizorogi Naomi,
Akasaka Takeshi,
Nagase Shigeru,
Martín Nazario,
Guldi Dirk M.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201100432
Subject(s) - porphyrin , chromophore , intramolecular force , covalent bond , chemistry , hybrid , information retrieval , computer science , stereochemistry , photochemistry , organic chemistry , botany , biology
π – π talks : Three isomeric porphyrin–La@C 82 hybrids were synthesized and structurally characterized for the first time (see picture: La blue sphere, N dark blue, O red). The two chromophores, which have a large π surface, evidently exhibit electronic interactions in the ground state and communicate with each other in the photoexcited state.