Dramatically Different Conductivity Properties of Metal–Organic Framework Polymorphs of Tl(TCNQ): An Unexpected Room‐Temperature Crystal‐to‐Crystal Phase Transition | Zendy

Avendano Carolina | Zendy; Zhang Zhongyue | Zendy; Ota Akira | Zendy; Zhao Hanhua | Zendy; Dunbar Kim R. | Zendy

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Dramatically Different Conductivity Properties of Metal–Organic Framework Polymorphs of Tl(TCNQ): An Unexpected Room‐Temperature Crystal‐to‐Crystal Phase Transition

Author(s) -

Avendano Carolina,

Zhang Zhongyue,

Ota Akira,

Zhao Hanhua,

Dunbar Kim R.

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201100372

Subject(s) - tetracyanoquinodimethane , crystal (programming language) , phase transition , phase (matter) , polymorphism (computer science) , crystallography , materials science , chemistry , chemical physics , condensed matter physics , physics , molecule , organic chemistry , computer science , genotype , gene , programming language , biochemistry

Just add water : Tl(TCNQ) polymorphs with very different charge‐transport properties have been isolated, one of which undergoes a remarkable crystal‐to‐crystal phase transition to the second phase when exposed to ambient water vapor (see picture; TCNQ=tetracyanoquinodimethane).

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