Enantioselective Total Synthesis of (−)‐Jiadifenolide | Zendy

Xu Jing | Zendy; Trzoss Lynnie | Zendy; Chang Weng K. | Zendy; Theodorakis Emmanuel A. | Zendy

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Enantioselective Total Synthesis of (−)‐Jiadifenolide

Author(s) -

Xu Jing,

Trzoss Lynnie,

Chang Weng K.,

Theodorakis Emmanuel A.

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201100313

Subject(s) - enantioselective synthesis , annulation , total synthesis , ring (chemistry) , computer science , stereochemistry , chemistry , combinatorial chemistry , information retrieval , world wide web , organic chemistry , catalysis

Neurofunk : Highlights of the synthesis of 1 , a potent modulator of neurotrophic factors, include construction of the B ring through an asymmetric Robinson annulation, assembly of the E ring lactone through a novel acid‐induced cascade reaction, and Pd 0 ‐mediated carbomethoxylation and methylation reactions for the construction of the C and A rings, respectively.

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