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Hexadecacobalt(II)‐Containing Polyoxometalate‐Based Single‐Molecule Magnet
Author(s) -
Ibrahim Masooma,
Lan Yanhua,
Bassil Bassem S.,
Xiang Yixian,
Suchopar Andreas,
Powell Annie K.,
Kortz Ulrich
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201100280
Subject(s) - polyoxometalate , magnet , molecule , cobalt , crystallography , single molecule magnet , phosphate , chemistry , materials science , nanotechnology , inorganic chemistry , physics , organic chemistry , magnetization , magnetic field , catalysis , quantum mechanics
POMs, magnets, and Co : The tetrameric 36‐tungsto‐8‐phosphate [{Co 4 (OH) 3 PO 4 } 4 (PW 9 O 34 ) 4 ] 28− containing 16 cobalt(II) centers was prepared by a simple, one‐pot synthetic procedure. The {Co 16 (OH) 12 (PO 4 ) 4 } 8+ core (see picture) exhibits single‐molecule magnetic behavior.