Hexadecacobalt(II)‐Containing Polyoxometalate‐Based Single‐Molecule Magnet | Zendy

Ibrahim Masooma | Zendy; Lan Yanhua | Zendy; Bassil Bassem S. | Zendy; Xiang Yixian | Zendy; Suchopar Andreas | Zendy; Powell Annie K. | Zendy; Kortz Ulrich | Zendy

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Hexadecacobalt(II)‐Containing Polyoxometalate‐Based Single‐Molecule Magnet

Author(s) -

Ibrahim Masooma,

Lan Yanhua,

Bassil Bassem S.,

Xiang Yixian,

Suchopar Andreas,

Powell Annie K.,

Kortz Ulrich

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201100280

Subject(s) - polyoxometalate , magnet , molecule , cobalt , crystallography , single molecule magnet , phosphate , chemistry , materials science , nanotechnology , inorganic chemistry , physics , organic chemistry , magnetization , magnetic field , catalysis , quantum mechanics

POMs, magnets, and Co : The tetrameric 36‐tungsto‐8‐phosphate [{Co 4 (OH) 3 PO 4 } 4 (PW 9 O 34 ) 4 ] 28− containing 16 cobalt(II) centers was prepared by a simple, one‐pot synthetic procedure. The {Co 16 (OH) 12 (PO 4 ) 4 } 8+ core (see picture) exhibits single‐molecule magnetic behavior.

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