Palladium(II)‐Triggered Rearrangement of Heptaphyrins to N‐Confused Porphyrins | Zendy

Yoneda Tomoki | Zendy; Saito Shohei | Zendy; Yorimitsu Hideki | Zendy; Osuka Atsuhiro | Zendy

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Palladium(II)‐Triggered Rearrangement of Heptaphyrins to N‐Confused Porphyrins

Author(s) -

Yoneda Tomoki,

Saito Shohei,

Yorimitsu Hideki,

Osuka Atsuhiro

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201100243

Subject(s) - metalation , porphyrin , palladium , chemistry , computer science , scheme (mathematics) , stereochemistry , combinatorial chemistry , philosophy , linguistics , photochemistry , mathematics , organic chemistry , catalysis , mathematical analysis

More confused : Metalation reactions of [32]heptaphyrins(1.1.1.1.1.1.1) with Pd II ions result in a rearrangement to form Pd II complexes that contain an N‐confused‐porphyrin (NCP) framework (see scheme). This rearrangement was also demonstrated for a monozinc(II) heptaphyrin complex with a figure‐eight conformation. The occurrence of these transformations shows that NCPs can now be considered a member of the expanded porphyrin family.

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