Iridium‐Catalyzed Intramolecular Asymmetric Allylic Dearomatization of Phenols | Zendy

Wu QingFeng | Zendy; Liu WenBo | Zendy; Zhuo ChunXiang | Zendy; Rong ZiQiang | Zendy; Ye KeYin | Zendy; You ShuLi | Zendy

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Iridium‐Catalyzed Intramolecular Asymmetric Allylic Dearomatization of Phenols

Author(s) -

Wu QingFeng,

Liu WenBo,

Zhuo ChunXiang,

Rong ZiQiang,

Ye KeYin,

You ShuLi

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201100206

Subject(s) - iridium , intramolecular force , allylic rearrangement , phosphoramidite , phenols , chemistry , ligand (biochemistry) , catalysis , diene , enantioselective synthesis , medicinal chemistry , combinatorial chemistry , organic chemistry , receptor , dna , biochemistry , natural rubber , oligonucleotide

Aromaticity lost : In the presence of [{Ir(cod)Cl} 2 ] and a binol‐derived phosphoramidite ligand, spirocyclohexadienone derivatives were obtained with up to 97 % ee through iridium‐catalyzed intramolecular asymmetric allylic dearomatization of phenols (see scheme; cod=cycloocta‐1,5‐diene).

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