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Memory Effects in Molecular Films of Free‐Standing Rod‐Shaped Ruthenium Complexes on an Electrode
Author(s) -
Terada Keiichi,
Kanaizuka Katsuhiko,
Iyer Vijay Mahadevan,
Sannodo Miyabi,
Saito Sohei,
Kobayashi Katsuaki,
Haga Masaaki
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201100142
Subject(s) - ruthenium , electrode , cathodic protection , oxidizing agent , information retrieval , computer science , anode , chemistry , materials science , optoelectronics , combinatorial chemistry , organic chemistry , catalysis
Forget me not : When an oxidizing voltage pulse was applied, ruthenium complexes immobilized on an ITO electrode showed a memory effect, and the original anodic photoresponse (see picture, above) changed to a cathodic one (below).