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Back Cover: Stereoselective Coordination of C 5 ‐Symmetric Corannulene Derivatives with an Enantiomerically Pure [Rh I (nbd*)] Metal Complex (Angew. Chem. Int. Ed. 4/2011)
Author(s) -
Bandera Davide,
Baldridge Kim K.,
Linden Anthony,
Dorta Reto,
Siegel Jay S.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201100017
Subject(s) - enantiopure drug , chemistry , metal , stereoselectivity , stereochemistry , corannulene , cover (algebra) , crystallography , enantioselective synthesis , molecule , organic chemistry , catalysis , mechanical engineering , engineering
Guided not by a foggy chiral memory but acting out of cold thermokinetic instinct, an enantiopure diene–metal complex, which barely registers a chiroptical signal, strikes adroitly at the heart of a floppy chiral corannulene, as it flails in form from right to left; thus ensues the resolution of the buckybowl's dynamic dance. Symmetry is lost in the recognition of a face, and the CD signature rises to reveal one hand, as described by K. K. Baldridge, J. S. Siegel et al. in their Communication on page 865 ff.