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Mizoroki–Heck‐Type Reaction Mediated by Potassium tert ‐Butoxide
Author(s) -
Shirakawa Eiji,
Zhang Xuejing,
Hayashi Tamio
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201008220
Subject(s) - halide , aryl , chemistry , catalysis , simple (philosophy) , heck reaction , styrene , potassium , organic chemistry , combinatorial chemistry , medicinal chemistry , computer science , palladium , philosophy , alkyl , polymer , epistemology , copolymer
In the absence of transition‐metal catalysts, a Mizoroki–Heck‐type reaction proceeded to give stilbene derivatives in a simple manner using an aryl halide, a styrene derivative, KO t Bu, EtOH, and DMF (see scheme; DMF= N , N ‐dimethylformamide).