Direct Palladium‐Catalyzed Intermolecular Allylation of Highly Electron‐Deficient Polyfluoroarenes | Zendy

Fan Shilu | Zendy; Chen Fei | Zendy; Zhang Xingang | Zendy

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Direct Palladium‐Catalyzed Intermolecular Allylation of Highly Electron‐Deficient Polyfluoroarenes

Author(s) -

Fan Shilu,

Chen Fei,

Zhang Xingang

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201008174

Subject(s) - regioselectivity , palladium , simple (philosophy) , computer science , scheme (mathematics) , catalysis , intermolecular force , transformation (genetics) , combinatorial chemistry , chemistry , information retrieval , organic chemistry , mathematics , molecule , philosophy , mathematical analysis , biochemistry , epistemology , gene

A simple operation : The use of readily available PPh 3 , high reaction efficiency, and good stereo‐ and regioselectivity provided useful and operationally simple access to polyfluoroarylated derivatives through the title transformation (see scheme; phen=1,10‐phenanthroline). The reaction mechanism was also studied.

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