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Direct Palladium‐Catalyzed Intermolecular Allylation of Highly Electron‐Deficient Polyfluoroarenes
Author(s) -
Fan Shilu,
Chen Fei,
Zhang Xingang
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201008174
Subject(s) - regioselectivity , palladium , simple (philosophy) , computer science , scheme (mathematics) , catalysis , intermolecular force , transformation (genetics) , combinatorial chemistry , chemistry , information retrieval , organic chemistry , mathematics , molecule , philosophy , mathematical analysis , biochemistry , epistemology , gene
A simple operation : The use of readily available PPh 3 , high reaction efficiency, and good stereo‐ and regioselectivity provided useful and operationally simple access to polyfluoroarylated derivatives through the title transformation (see scheme; phen=1,10‐phenanthroline). The reaction mechanism was also studied.