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A Family of Heterometallic Cubane‐Type Clusters with an exo ‐Fe(CO) 3 Fragment Anchored to the Cubane
Author(s) -
Geetharani K.,
Bose Shubhankar Kumar,
Sahoo Satyanarayan,
Ghosh Sundargopal
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201008101
Subject(s) - cubane , crystallography , moiety , type (biology) , chemistry , stereochemistry , crystal structure , geology , paleontology
Metal‐rich metallaboranes : An exo ‐Fe(CO) 3 moiety linked to a cubane core is the most prominent feature of complexes [(Cp*M) 2 (μ 3 ‐E) 2 B 2 H(μ‐H){Fe(CO) 2 } 2 Fe(CO) 3 ] (M=Mo, E=S, Se; M=Ru, E=CO; Cp*=η 5 ‐C 5 Me 5 ), which are the first heterobimetallic cubane‐type clusters with a boride unit (see structure).