Stannylene or Metallastanna(IV)ocane: A Matter of Formalism | Zendy

Brendler Erica | Zendy; Wächtler Erik | Zendy; Heine Thomas | Zendy; Zhechkov Lyuben | Zendy; Langer Thorsten | Zendy; Pöttgen Rainer | Zendy; Hill Anthony F. | Zendy; Wagler Jörg | Zendy

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Stannylene or Metallastanna(IV)ocane: A Matter of Formalism

Author(s) -

Brendler Erica,

Wächtler Erik,

Heine Thomas,

Zhechkov Lyuben,

Langer Thorsten,

Pöttgen Rainer,

Hill Anthony F.,

Wagler Jörg

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201007967

Subject(s) - palladium , formalism (music) , donation , chemistry , crystallography , stereochemistry , political science , law , organic chemistry , art , musical , visual arts , catalysis

Pushmi‐pullyu with palladium : Although created by σ donation from SnCl 2 to a Pd II complex, the SnPd bonds in the compounds depicted exhibit formal σ donation in the opposite direction. Computational and spectroscopic data support stannylpalladium (Pd I Sn III ) and palladastanna(IV)ocane (Pd 0 →Sn IV ) descriptions over stannylene coordination.

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