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Stannylene or Metallastanna(IV)ocane: A Matter of Formalism
Author(s) -
Brendler Erica,
Wächtler Erik,
Heine Thomas,
Zhechkov Lyuben,
Langer Thorsten,
Pöttgen Rainer,
Hill Anthony F.,
Wagler Jörg
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201007967
Subject(s) - palladium , formalism (music) , donation , chemistry , crystallography , stereochemistry , political science , law , organic chemistry , art , musical , visual arts , catalysis
Pushmi‐pullyu with palladium : Although created by σ donation from SnCl 2 to a Pd II complex, the SnPd bonds in the compounds depicted exhibit formal σ donation in the opposite direction. Computational and spectroscopic data support stannylpalladium (Pd I Sn III ) and palladastanna(IV)ocane (Pd 0 →Sn IV ) descriptions over stannylene coordination.