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A Fischer Carbene within an Arduengo Carbene
Author(s) -
Ruiz Javier,
García Lucía,
Perandones Bernabé F.,
Vivanco Marilín
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201007937
Subject(s) - carbene , trifluoromethanesulfonate , alkylation , chemistry , transition metal carbene complex , metal , ion , polymer chemistry , medicinal chemistry , stereochemistry , organic chemistry , catalysis
A Fischer carbene complex within the N‐heterocyclic carbene skeleton is present in Mn I /Au I heterometallic compounds that were synthesized from an acyclic diaminocarbene complex, through a translocation process of metallic ions under basic conditions and subsequent alkylation with methyl triflate (see scheme; bipy=bipyridyl, [Mn]=[Mn(CO) 2 (bipy)]).