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Transition‐Metal‐Catalyzed Carboxylation of CH Bonds
Author(s) -
Ackermann Lutz
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201007883
Subject(s) - carboxylation , catalysis , transition metal , bond , chemistry , organic chemistry , business , finance
CO 2 in a fix : Gold and copper complexes of N‐heterocyclic carbenes recently enabled efficient direct carboxylation of (hetero)arenes having moderately acidic CH bonds under remarkably mild reaction conditions (IPr=1,3‐bis(2,6‐diisopropylphenyl)imidazol‐2‐ylidene).