Tuning the Spin State of Cobalt in a Co–La Heterometallic Complex through Controllable Coordination Sphere of La | Zendy

Bao SongSong | Zendy; Liao Yi | Zendy; Su YanHui | Zendy; Liang Xu | Zendy; Hu FengChun | Zendy; Sun Zhihu | Zendy; Zheng LiMin | Zendy; Wei Shiqiang | Zendy; Alberto Roger | Zendy; Li YiZhi | Zendy; Ma Jing | Zendy

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Tuning the Spin State of Cobalt in a Co–La Heterometallic Complex through Controllable Coordination Sphere of La

Author(s) -

Bao SongSong,

Liao Yi,

Su YanHui,

Liang Xu,

Hu FengChun,

Sun Zhihu,

Zheng LiMin,

Wei Shiqiang,

Alberto Roger,

Li YiZhi,

Ma Jing

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201007872

Subject(s) - cobalt , coordination sphere , spin (aerodynamics) , state (computer science) , moment (physics) , crystallography , spin states , dehydration , chemistry , materials science , physics , condensed matter physics , computer science , inorganic chemistry , quantum mechanics , thermodynamics , crystal structure , algorithm , biochemistry

Reversible dehydration of complex 1 switches the spin state of cobalt from low‐spin (LS) Co III to high‐spin (HS) Co II (see picture) and allows the magnetic moment to be varied from 0.48 μ B at 120 °C to 4.15 μ B at 220 °C in fully dehydrated complex 1‐220 . notpH 6 =1,4,7‐triazacyclononane‐1,4,7‐triyl‐tris(methylenephosphonic acid).

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