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Efficient Loading and Kinetic Trapping of Hexameric Pyrogallolarene Capsules in Solution
Author(s) -
Kvasnica Miroslav,
Chapin Jennifer C.,
Purse Byron W.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201007800
Subject(s) - schematic , solvent , kinetic energy , trapping , thermal , computer science , chemistry , physics , thermodynamics , organic chemistry , engineering , biology , electronic engineering , ecology , quantum mechanics
Solvent matters : By carrying out the assembly of pyrogallolarene hexamers under thermal conditions in the absence of solvent, highly efficient loading of guest molecules to produce kinetically trapped assemblies was achieved. Such products are not formed when the solvents are present (see schematic).