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Stereospecific Copper‐Catalyzed CH Allylation of Electron‐Deficient Arenes with Allyl Phosphates
Author(s) -
Yao Tomoyuki,
Hirano Koji,
Satoh Tetsuya,
Miura Masahiro
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201007733
Rapid and concise : The title reaction proceeds via copper complexes in a highly stereospecific manner (see scheme; acac=acetylacetonate, phen=1,10‐phenanthroline, TBS= t BuMe 2 Si). The catalysis provides a rapid and concise route to allylarenes that contain fluorinated aromatic cores of an electron‐deficient nature.