A Novel Ligand for the Enantioselective Ruthenium‐Catalyzed Olefin Metathesis | Zendy

Kannenberg Axel | Zendy; Rost Daniel | Zendy; Eibauer Stefan | Zendy; Tiede Sascha | Zendy; Blechert Siegfried | Zendy

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A Novel Ligand for the Enantioselective Ruthenium‐Catalyzed Olefin Metathesis

Author(s) -

Kannenberg Axel,

Rost Daniel,

Eibauer Stefan,

Tiede Sascha,

Blechert Siegfried

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201007673

Subject(s) - ruthenium , enantioselective synthesis , carbene , metathesis , olefin metathesis , catalysis , ligand (biochemistry) , chemistry , combinatorial chemistry , chirality (physics) , stereochemistry , computer science , organic chemistry , physics , polymerization , particle physics , biochemistry , chiral symmetry breaking , receptor , nambu–jona lasinio model , quark , polymer

A bridge connects and efficiently transfers the chirality from the backbone of a N‐heterocyclic carbene (NHC) to the metal center. The result is excellent enantioselectivities in the ruthenium‐catalyzed, asymmetric ring‐opening cross‐metathesis of norbornenes with allyltrimethylsilane (see scheme).

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