A Metal–Organic Framework with Optimized Open Metal Sites and Pore Spaces for High Methane Storage at Room Temperature | Zendy

Guo Zhiyong | Zendy; Wu Hui | Zendy; Srinivas Gadipelli | Zendy; Zhou Yaming | Zendy; Xiang Shengchang | Zendy; Chen Zhenxia | Zendy; Yang Yongtai | Zendy; Zhou Wei | Zendy; O'Keeffe Michael | Zendy; Chen Banglin | Zendy

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A Metal–Organic Framework with Optimized Open Metal Sites and Pore Spaces for High Methane Storage at Room Temperature

Author(s) -

Guo Zhiyong,

Wu Hui,

Srinivas Gadipelli,

Zhou Yaming,

Xiang Shengchang,

Chen Zhenxia,

Yang Yongtai,

Zhou Wei,

O'Keeffe Michael,

Chen Banglin

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201007583

Subject(s) - methane , volume (thermodynamics) , key (lock) , metal organic framework , bar (unit) , porosity , computer science , materials science , environmental science , process engineering , chemistry , physics , engineering , operating system , organic chemistry , composite material , thermodynamics , meteorology , adsorption

Holey MOF! Open copper sites and optimal pore spaces in UTSA‐20 (see picture), a MOF based on the novel trinodal (3,3,4) net, has made UTSA‐20 into the material with the highest methane storage density (0.22 g cm −3 ) in micropores, and one of the few porous MOFs with storage volume capacity (195 cm 3 cm −3 ) surpassing the DOE methane target of 180 cm 3 cm −3 at room temperature and 35 bar.

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