Highly Selective Decarbonylation of 5‐(Hydroxymethyl)furfural in the Presence of Compressed Carbon Dioxide | Zendy

Geilen Frank M. A. | Zendy; vom Stein Thorsten | Zendy; Engendahl Barthel | Zendy; Winterle Sonja | Zendy; Liauw Marcel A. | Zendy; Klankermayer Jürgen | Zendy; Leitner Walter | Zendy

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Highly Selective Decarbonylation of 5‐(Hydroxymethyl)furfural in the Presence of Compressed Carbon Dioxide

Author(s) -

Geilen Frank M. A.,

vom Stein Thorsten,

Engendahl Barthel,

Winterle Sonja,

Liauw Marcel A.,

Klankermayer Jürgen,

Leitner Walter

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201007582

Subject(s) - decarbonylation , furfural , furfuryl alcohol , hydroxymethyl , iridium , phosphine , chemistry , catalysis , carbon dioxide , organic chemistry , ruthenium , alcohol

Less is more : The integrated development and optimization of catalysts and reaction media led to a highly selective decarbonylation of 5‐(hydroxymethyl)furfural (HMF) to furfuryl alcohol (FFA) with an iridium/phosphine catalyst in the presence of compressed carbon dioxide. Subsequent hydrogenation over ruthenium nanoparticles (RuNPs) led to tetrahydrofurfuryl alcohol (THFA), a possible solvent for the decarbonylation reaction (see scheme).

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