Cyclo[8]isoindoles: Ring‐Expanded and Annelated Porphyrinoids | Zendy

Okujima Tetsuo | Zendy; Jin Guangnan | Zendy; Matsumoto Naoki | Zendy; Mack John | Zendy; Mori Shigeki | Zendy; Ohara Keishi | Zendy; Kuzuhara Daiki | Zendy; Ando Chie | Zendy; Ono Noboru | Zendy; Yamada Hiroko | Zendy; Uno Hidemitsu | Zendy; Kobayashi Nagao | Zendy

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Cyclo[8]isoindoles: Ring‐Expanded and Annelated Porphyrinoids

Author(s) -

Okujima Tetsuo,

Jin Guangnan,

Matsumoto Naoki,

Mack John,

Mori Shigeki,

Ohara Keishi,

Kuzuhara Daiki,

Ando Chie,

Ono Noboru,

Yamada Hiroko,

Uno Hidemitsu,

Kobayashi Nagao

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201007510

Subject(s) - isoindole , pyrrole , ring (chemistry) , chemistry , computational chemistry , stereochemistry , organic chemistry

Retro : Cyclo[8]isoindole, which has a saddle‐shaped geometry (see picture, 2 ), was synthesized by oxidative coupling of a bicyclo[2.2.2]octadiene(BCOD)‐fused 2,2′‐bipyrrole followed by a retro‐Diels–Alder reaction of BCOD‐fused cyclo[8]pyrrole ( 1 ). Key trends in the optical spectra of ring‐annelated cyclo[8]pyrroles are identified based on magnetic circular dichroism spectra and theorectical calculations.

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