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Electrochemically Triggered Assembly of Films: A One‐Pot Morphogen‐Driven Buildup
Author(s) -
Rydzek Gaulthier,
Jierry Loïc,
Parat Audrey,
Thomann JeanSébastien,
Voegel JeanClaude,
Senger Bernard,
Hemmerlé Joseph,
Ponche Arnaud,
Frisch Benoît,
Schaaf Pierre,
Boulmedais Fouzia
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201007436
Subject(s) - morphogen , supramolecular chemistry , alkyne , azide , click chemistry , polymer , computer science , nanotechnology , combinatorial chemistry , chemistry , materials science , organic chemistry , catalysis , molecule , biochemistry , gene
Polymers that “click” : A polymer film is obtained by the Cu I ‐catalyzed Sharpless click reaction between two polymers, bearing either azide or alkyne groups, both present simultaneously in a Cu II solution (see picture). The Cu I morphogen is generated at an electrode by applying an adequate potential. This concept can be extended to supramolecular films formed by coordination complexes.