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A Mixed‐Spin Molecular Square with a Hybrid [2×2]Grid/Metallocyclic Architecture
Author(s) -
Li Feng,
Clegg Jack K.,
GouxCapes Laurence,
Chastanet Guillaume,
D'Alessandro Deanna M.,
Létard JeanFrançois,
Kepert Cameron J.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201007409
Subject(s) - grid , architecture , computer science , spin (aerodynamics) , crystallography , physics , chemistry , mathematics , geometry , visual arts , art , thermodynamics
Hunting high and low : A cyanide‐bridged rhombic mixed‐spin Fe II –Fe II complex that features low‐spin (LS) and high‐spin (HS) Fe II centers was prepared by self‐assembly including the decomposition of SeCN. The structural motif represents a hybrid [2×2]grid/metallocyclic architecture (see picture).