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Synergy of Homogeneous and Heterogeneous Chemistry Probed by In Situ Spatially Resolved Measurements of Temperature and Composition
Author(s) -
Donazzi Alessandro,
Livio Dario,
Maestri Matteo,
Beretta Alessandra,
Groppi Gianpiero,
Tronconi Enrico,
Forzatti Pio
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201007346
Subject(s) - pyrolytic carbon , in situ , homogeneous , kinetics , catalysis , chemistry , partial oxidation , phase (matter) , chemical engineering , chemical physics , thermodynamics , pyrolysis , organic chemistry , physics , quantum mechanics , engineering
By land or by air : Ultrafast catalytic processes for converting hydrocarbons at short contact times are characterized by extremely severe operating conditions. In situ sampling and detailed modeling of surface and gas‐phase kinetics allowed the elucidation of the complex interplay between heterogeneous and homogenous pyrolytic routes to H 2 and CO in the catalytic partial oxidation (CPO) of C 3 H 8 .