Concise Synthesis and Crystal Structure of [12]Cycloparaphenylene | Zendy

Segawa Yasutomo | Zendy; Miyamoto Shinpei | Zendy; Omachi Haruka | Zendy; Matsuura Sanae | Zendy; Šenel Petr | Zendy; Sasamori Takahiro | Zendy; Tokitoh Norihiro | Zendy; Itami Kenichiro | Zendy

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Concise Synthesis and Crystal Structure of [12]Cycloparaphenylene

Author(s) -

Segawa Yasutomo,

Miyamoto Shinpei,

Omachi Haruka,

Matsuura Sanae,

Šenel Petr,

Sasamori Takahiro,

Tokitoh Norihiro,

Itami Kenichiro

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201007232

Subject(s) - crystal structure , molecule , cyclohexane , crystallography , ring (chemistry) , crystal (programming language) , chemistry , materials science , stereochemistry , computer science , organic chemistry , programming language

Crystal clear : The title macrocycle was constructed by a nickel‐mediated shotgun macrocyclization. The X‐ray crystallographic structure of [12]CPP revealed a circular structure incorporating two cyclohexane molecules within the ring. The [12]CPP molecules were also found to crystallize into tubular and herringbone structures.

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