S‐Benzimidazolyl Glycosides as a Platform for Oligosaccharide Synthesis by an Active–Latent Strategy | Zendy

Hasty Scott J. | Zendy; Kleine Matthew A. | Zendy; Demchenko Alexei V. | Zendy

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S‐Benzimidazolyl Glycosides as a Platform for Oligosaccharide Synthesis by an Active–Latent Strategy

Author(s) -

Hasty Scott J.,

Kleine Matthew A.,

Demchenko Alexei V.

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201007212

Subject(s) - moiety , glycosylation , anomer , oligosaccharide , carbohydrate synthesis , chemistry , alkylation , computer science , stereochemistry , combinatorial chemistry , biochemistry , carbohydrate , catalysis

Doing the Biz : The S ‐benzimidazolyl (SBiz) anomeric moiety is a new leaving group that can be activated for glycosylation under a variety of conditions, including metal‐assisted and alkylation pathways. Application of a substituted SBiz moiety (X=anisoyl, see picture) allows active–latent and armed–disarmed types of oligosaccharide assembly.

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