Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand | Zendy

Moret MarcEtienne | Zendy; Peters Jonas C. | Zendy

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Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand

Author(s) -

Moret MarcEtienne,

Peters Jonas C.

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201006918

Subject(s) - borane , chemistry , tris , ligand (biochemistry) , boron , trigonal bipyramidal molecular geometry , imide , crystallography , trigonal crystal system , rhodium , photochemistry , inorganic chemistry , polymer chemistry , crystal structure , catalysis , organic chemistry , receptor , biochemistry

Adaptable metallaboratranes : A tris‐ (phosphino)borane ligand stabilizes both low‐valent FeN 2 complexes and a mid‐valent imido species with a FeNAr bond, thanks to its ability to shuttle between trigonal‐bipyramidal and pseudotetrahedral geometries by elongation of the apical iron–boron bond (see picture).

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