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Singly N‐Confused [26]Hexaphyrin: A Binucleating Porphyrinoid Ligand for Mixed Metals in Different Oxidation States
Author(s) -
Gokulnath Sabapathi,
Yamaguchi Keisuke,
Toganoh Motoki,
Mori Shigeki,
Uno Hidemitsu,
Furuta Hiroyuki
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201006784
Subject(s) - chemistry , crystallography , combinatorial chemistry , nanotechnology , information retrieval , computer science , materials science
Mix and match : The title porphyrinoid has been synthesized and shows unique coordination chemistry by incorporating two different metals with different oxidation states (see figure). X‐ray crystallography was used to confirm that a rectangular conformation in both mono‐ and binuclear complexes was retained.
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