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An Efficient and General Iron‐Catalyzed CC Bond Activation with 1,3‐Dicarbonyl Units as a Leaving Groups
Author(s) -
Li Huanrong,
Li Wenjuan,
Liu Weiping,
He Zhiheng,
Li Zhiping
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201006779
Subject(s) - indene , chemistry , catalysis , complement (music) , bond cleavage , friedel–crafts reaction , combinatorial chemistry , computer science , stereochemistry , medicinal chemistry , organic chemistry , biochemistry , complementation , gene , phenotype
With our compliments : The 1,3‐dicarbonyl unit has been shown to be a new and useful leaving group for iron‐catalyzed bond cleavage (see scheme). This new strategy can complement the traditional Friedel–Crafts reaction and was applied in the synthesis of indene derivatives.