Synthesis and Characterization of the Dicopper(II)‐Containing 22‐Palladate(II)[Cu II  2 Pd II  22 P V  12 O 60 (OH) 8 ] 20− | Zendy

BarsukovaStuckart Maria | Zendy; Izarova Natalya V. | Zendy; Jameson Geoffrey B. | Zendy; Ramachandran Vasanth | Zendy; Wang Zhenxing | Zendy; van Tol Johan | Zendy; Dalal Naresh S. | Zendy; Ngo Biboum Rosa | Zendy; Keita Bineta | Zendy; Nadjo Louis | Zendy; Kortz Ulrich | Zendy

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Synthesis and Characterization of the Dicopper(II)‐Containing 22‐Palladate(II)[Cu II 2 Pd II 22 P V 12 O 60 (OH) 8 ] 20−

Author(s) -

BarsukovaStuckart Maria,

Izarova Natalya V.,

Jameson Geoffrey B.,

Ramachandran Vasanth,

Wang Zhenxing,

van Tol Johan,

Dalal Naresh S.,

Ngo Biboum Rosa,

Keita Bineta,

Nadjo Louis,

Kortz Ulrich

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201006734

Subject(s) - crystallography , ion , chemistry , crystal structure , characterization (materials science) , physics , materials science , nanotechnology , organic chemistry

A couple of coppers : Two Cu II ions exhibit highly distorted cubic coordination and unexpectedly large magnetic exchange coupling in a discrete dicopper(II)‐containing 22‐palladate(II). The compound is isolated as the hydrated sodium salt Na 20 [Cu II 2 Pd II 22 P V 12 O 60 (OH) 8 ]⋅58 H 2 O ( 1 ) in which the polyanion (see structure: Cu turquoise, Pd blue, O red balls, {PO 4 } purple tetrahedra) is the largest noble metalate reported to date.

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