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Two Linear Undecanickel Mixed‐Valence Complexes: Increasing the Size and the Scope of the Electronic Properties of Nickel Metal Strings
Author(s) -
Ismayilov Rayyat H.,
Wang WenZhen,
Lee GeneHsiang,
Yeh ChenYu,
Hua ShaoAn,
Song You,
Rohmer MarieMadeleine,
Bénard Marc,
Peng ShieMing
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201006695
Subject(s) - nickel , scope (computer science) , valence (chemistry) , metal , planar , chain (unit) , chemistry , computer science , crystallography , materials science , physics , metallurgy , organic chemistry , quantum mechanics , computer graphics (images) , programming language
Nickel′s eleven : A metal chain consisting of four dinuclear mixed‐valent Ni 2 3+ units linked together by three square‐planar Ni 2+ units has been prepared (see picture of the real molecular model in the lobby of the chemistry building at National Taiwan University). The electronic and magnetic properties of this linear complex containing 11 nickel atoms are reported.