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Diversity‐Oriented Synthesis of Polycyclic Scaffolds by Modification of an Anodic Product Derived from 2,4‐Dimethylphenol
Author(s) -
Barjau Joaquin,
Schnakenburg Gregor,
Waldvogel Siegfried R.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201006637
Subject(s) - chemoselectivity , anode , reactivity (psychology) , anodic oxidation , diversity (politics) , product (mathematics) , chemistry , polymer chemistry , materials science , organic chemistry , mathematics , catalysis , electrode , sociology , medicine , alternative medicine , geometry , pathology , anthropology
Like a Swiss army knife : The pentacycle shown, which results from the anodic oxidation of 2,4‐dimethylphenol, displays a wealth of potential reactivity. Depending on the applied reaction conditions a variey of polycyclic architectures are obtained with impressive stereo‐, regio‐, and chemoselectivity.