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Three‐Dimensional Covalent Co‐Assembly between Inorganic Supertetrahedral Clusters and Imidazolates
Author(s) -
Wu Tao,
Khazhakyan Ripsime,
Wang Le,
Bu Xianhui,
Zheng ShouTian,
Chau Victoria,
Feng Pingyun
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201006531
Subject(s) - chalcogenide , covalent bond , imidazolate , chemistry , crystallography , nanotechnology , materials science , inorganic chemistry , organic chemistry
An unlikely marriage between chalcogenide clusters and imidazolates leads to a family of 3D covalent arrays of supertetrahedral chalcogenide clusters and imidazolate ligands (see picture). These are the first examples of supertetrahedral clusters being assembled with anionic ligands.