Oxocyclohexadienylidene‐Substituted Subporphyrins | Zendy

Hayashi Shinya | Zendy; Sung Jooyoung | Zendy; Sung Young Mo | Zendy; Inokuma Yasuhide | Zendy; Kim Dongho | Zendy; Osuka Atsuhiro | Zendy

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Oxocyclohexadienylidene‐Substituted Subporphyrins

Author(s) -

Hayashi Shinya,

Sung Jooyoung,

Sung Young Mo,

Inokuma Yasuhide,

Kim Dongho,

Osuka Atsuhiro

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201006449

Subject(s) - tris , deprotonation , delocalized electron , chemistry , electron delocalization , scheme (mathematics) , combinatorial chemistry , computer science , information retrieval , stereochemistry , organic chemistry , mathematics , biochemistry , ion , mathematical analysis

Quinonoidal subporphyrin analogue 2 was synthesized by oxidation of meso‐ tris(3,5‐di‐ tert ‐butyl‐4‐hydroxyphenyl)subporphyrin 1 (see scheme). Compound 2 was readily deprotonated to generate anionic species 3 . These three macrocycles were structurally characterized, including the full delocalization of the anionic charge in 3 .

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