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Deacylative Allylation of Nitroalkanes: Unsymmetric Bisallylation by a Three‐Component Coupling
Author(s) -
Grenning Alexander J.,
Tunge Jon A.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201006273
Subject(s) - allylic rearrangement , electrophile , component (thermodynamics) , coupling (piping) , chemistry , nucleophile , combinatorial chemistry , coupling reaction , organic chemistry , materials science , catalysis , physics , metallurgy , thermodynamics
Use it and lose it! Allylic alcohols were used directly for the synthesis of diallylated nitroalkanes in a three‐component coupling based on the strategy of deacylative allylation for the in situ generation of a nucleophile and an allyl electrophile (see scheme).
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