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Facile Catalytic Hydrosilylation of Pyridines
Author(s) -
Gutsulyak Dmitry V.,
van der Est Art,
Nikonov Georgii I.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201006135
Subject(s) - hydrosilylation , catalysis , regioselectivity , chemistry , phenanthroline , combinatorial chemistry , medicinal chemistry , organic chemistry
Not only surprisingly facile , a hydrosilylation of pyridines under the catalysis of [Cp( i Pr 3 P)Ru(NCCH 3 ) 2 ] + has the advantages that it is 1,4‐regioselective and reversible. The products can be transformed in a variety of ways (see scheme). The related complex [CpRu(NCCH 3 ) 3 ] + catalyzes the two‐hydrogen‐atom reduction of phenanthroline by HSiMe 2 Ph/water.
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