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In Situ Spectroelectrochemical Investigation of Electrocatalytic Microbial Biofilms by Surface‐Enhanced Resonance Raman Spectroscopy
Author(s) -
Millo Diego,
Harnisch Falk,
Patil Sunil A.,
Ly Hoang K.,
Schröder Uwe,
Hildebrandt Peter
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201006046
Subject(s) - raman spectroscopy , raman scattering , cyclic voltammetry , biofilm , resonance (particle physics) , electron transfer , in situ , electrode , resonance raman spectroscopy , chemistry , voltammetry , electrochemistry , analytical chemistry (journal) , nanotechnology , materials science , bacteria , photochemistry , physics , optics , biology , organic chemistry , particle physics , genetics
A mixed‐culture‐derived microbial biofilm, grown on silver electrodes, was studied in vivo with surface‐enhanced resonance Raman scattering (SERRS) in combination with cyclic voltammetry. This experimental approach provides unprecedented structural information about the outer membrane cytochromes involved in the direct electron transfer across the bacterium–electrode interface.

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