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Hybrid Zeolitic Imidazolate Frameworks with Catalytically Active TO 4 Building Blocks
Author(s) -
Wang Fei,
Liu ZiSheng,
Yang Hui,
Tan YanXi,
Zhang Jian
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201005917
Subject(s) - zeolitic imidazolate framework , imidazolate , catalysis , tetrahedron , thermal stability , materials science , zinc , computer science , topology (electrical circuits) , nanotechnology , chemistry , metal organic framework , crystallography , organic chemistry , engineering , adsorption , metallurgy , electrical engineering
Catalytic cavities : Hybrid zeolitic imidazolate frameworks (HZIFs) integrate compositional and structural features of inorganic zeolites and zeolitic imidazolate frameworks (ZIFs). The combination of catalytically active TO 4 tetrahedra with zinc–imidazolate units leads to a new kind of porous material with distinct framework topology, unusual high thermal stability, and catalytic properties.