An Organometallic Nanosized Capsule Consisting of  cyclo ‐P 5  Units and Copper(I) Ions | Zendy

Welsch Stefan | Zendy; Gröger Christian | Zendy; Sierka Marek | Zendy; Scheer Manfred | Zendy

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An Organometallic Nanosized Capsule Consisting of cyclo ‐P 5 Units and Copper(I) Ions

Author(s) -

Welsch Stefan,

Gröger Christian,

Sierka Marek,

Scheer Manfred

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201005910

Subject(s) - group 2 organometallic chemistry , copper , molecule , crystallography , organometallic chemistry , ion , capsule , cohesion (chemistry) , polymer , chemistry , stereochemistry , materials science , nanotechnology , geology , crystal structure , organic chemistry , paleontology

A giant organometallic molecule and a 2D coordination polymer are formed by template‐assisted self‐assembly between CuCl and the cyclo ‐P 5 complex [Cp*Fe(η 5 ‐P 5 )]. The giant capsular molecule exhibits a skeleton of 110 inorganic core atoms and consists of two half‐shells with threefold symmetry. Dipersion forces between two encapsulated [Cp*Fe(η 5 ‐P 5 )] guest complexes and half‐shells are responsible for the cohesion of the capsule (see structure and model; Cp*=η 5 ‐C 5 Me 5 ).

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