Tris(polyalkylcyclopentadienyl) Complexes: The Elusive [(η 5 ‐C 5 R 5 ) 2 M(η 1 ‐C 5 R 5 )] Structure and Trihapto Cyclopentadienyl Coordination Involving a Methyl Substituent | Zendy

Demir Selvan | Zendy; Mueller Thomas J. | Zendy; Ziller Joseph W. | Zendy; Evans William J. | Zendy

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Tris(polyalkylcyclopentadienyl) Complexes: The Elusive [(η 5 ‐C 5 R 5 ) 2 M(η 1 ‐C 5 R 5 )] Structure and Trihapto Cyclopentadienyl Coordination Involving a Methyl Substituent

Author(s) -

Demir Selvan,

Mueller Thomas J.,

Ziller Joseph W.,

Evans William J.

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201005898

Subject(s) - tris , content (measure theory) , group 2 organometallic chemistry , surprise , atom (system on chip) , chemistry , crystallography , physics , computer science , molecule , organic chemistry , mathematics , psychology , social psychology , biochemistry , embedded system , mathematical analysis

Classics surprise : Exploration of the (C 5 Me 4 H) − chemistry of Sc, Y, and Lu metallocenes has led to the first example of a bis(η 5 )(η 1 )‐tris(polyalkylcyclopentadienyl) complex and a new three‐atom coordination mode for polyalkylcyclopentadienyl ligands (see scheme).

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