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Tris(polyalkylcyclopentadienyl) Complexes: The Elusive [(η 5 ‐C 5 R 5 ) 2 M(η 1 ‐C 5 R 5 )] Structure and Trihapto Cyclopentadienyl Coordination Involving a Methyl Substituent
Author(s) -
Demir Selvan,
Mueller Thomas J.,
Ziller Joseph W.,
Evans William J.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201005898
Subject(s) - tris , content (measure theory) , group 2 organometallic chemistry , surprise , atom (system on chip) , chemistry , crystallography , physics , computer science , molecule , organic chemistry , mathematics , psychology , social psychology , biochemistry , embedded system , mathematical analysis
Classics surprise : Exploration of the (C 5 Me 4 H) − chemistry of Sc, Y, and Lu metallocenes has led to the first example of a bis(η 5 )(η 1 )‐tris(polyalkylcyclopentadienyl) complex and a new three‐atom coordination mode for polyalkylcyclopentadienyl ligands (see scheme).