An Oxocobalt(IV) Complex Stabilized by Lewis Acid Interactions with Scandium(III) Ions | Zendy

Pfaff Florian Felix | Zendy; Kundu Subrata | Zendy; Risch Marcel | Zendy; Pandian Shanthi | Zendy; Heims Florian | Zendy; PryjomskaRay Iweta | Zendy; Haack Peter | Zendy; Metzinger Ramona | Zendy; Bill Eckhard | Zendy; Dau Holger | Zendy; Comba Peter | Zendy; Ray Kallol | Zendy

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An Oxocobalt(IV) Complex Stabilized by Lewis Acid Interactions with Scandium(III) Ions

Author(s) -

Pfaff Florian Felix,

Kundu Subrata,

Risch Marcel,

Pandian Shanthi,

Heims Florian,

PryjomskaRay Iweta,

Haack Peter,

Metzinger Ramona,

Bill Eckhard,

Dau Holger,

Comba Peter,

Ray Kallol

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201005869

Subject(s) - scandium , lewis acids and bases , chemistry , ion , inorganic chemistry , organic chemistry , catalysis

An elusive S =3/2 oxocobalt(IV) complex is stabilized by a Lewis acid interaction with a scandium(III) ion. The {Co IV ‐O‐Sc} 3+ unit, characterized by spectroscopic and DFT methods, is a stronger electron‐transfer and H‐atom abstraction agent but weaker oxo‐transfer agent than the corresponding {Fe IV O} complex (see scheme; L=tris[2‐( N ‐tetramethylguanidyl)ethyl]amine).

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