Carbon–Nitrogen Bond Formation by the Reaction of 1,2‐Cumulenes with a Ditantalum Complex Containing Side‐On‐ and End‐On‐Bound Dinitrogen | Zendy

Ballmann Joachim | Zendy; Yeo Alyssa | Zendy; Patrick Brian O. | Zendy; Fryzuk Michael D. | Zendy

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Carbon–Nitrogen Bond Formation by the Reaction of 1,2‐Cumulenes with a Ditantalum Complex Containing Side‐On‐ and End‐On‐Bound Dinitrogen

Author(s) -

Ballmann Joachim,

Yeo Alyssa,

Patrick Brian O.,

Fryzuk Michael D.

Publication year - 2011

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201005704

Subject(s) - chemistry , cycloaddition , nitrogen , carbon fibers , carbon disulfide , side chain , tantalum , cumulene , polymer chemistry , double bond , photochemistry , molecule , organic chemistry , materials science , catalysis , polymer , composite number , composite material

Some dinitrogen on the side : 1,2‐cumulenes, such as carbodiimides, carbon disulfide, and isothiocyanates, react with the side‐on end‐on N 2 tantalum complex through a [2+2] cycloaddition pathway to result in the formation of new carbon–nitrogen bonds.

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