Premium
Carbon–Nitrogen Bond Formation by the Reaction of 1,2‐Cumulenes with a Ditantalum Complex Containing Side‐On‐ and End‐On‐Bound Dinitrogen
Author(s) -
Ballmann Joachim,
Yeo Alyssa,
Patrick Brian O.,
Fryzuk Michael D.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201005704
Subject(s) - chemistry , cycloaddition , nitrogen , carbon fibers , carbon disulfide , side chain , tantalum , cumulene , polymer chemistry , double bond , photochemistry , molecule , organic chemistry , materials science , catalysis , polymer , composite number , composite material
Some dinitrogen on the side : 1,2‐cumulenes, such as carbodiimides, carbon disulfide, and isothiocyanates, react with the side‐on end‐on N 2 tantalum complex through a [2+2] cycloaddition pathway to result in the formation of new carbon–nitrogen bonds.