Bipolar Patterning of Conducting Polymers by Electrochemical Doping and Reaction | Zendy

Inagi Shinsuke | Zendy; Ishiguro Yutaka | Zendy; Atobe Mahito | Zendy; Fuchigami Toshio | Zendy

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Bipolar Patterning of Conducting Polymers by Electrochemical Doping and Reaction

Author(s) -

Inagi Shinsuke,

Ishiguro Yutaka,

Atobe Mahito,

Fuchigami Toshio

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201005671

Subject(s) - electrode , electrolyte , electrochemistry , doping , polymer , materials science , optoelectronics , nanotechnology , computer science , chemistry , composite material

On the double : When a poly(3‐methylthiophene) (PT) film is doped on a bipolar electrode with Bu 4 NPF 6 as supporting electrolyte, the film includes PF 6 − anions with a composition gradient along the potential gradient on the electrode. The use of Et 4 NCl results in partial chlorination of the PT film that reflects the potential gradient of the bipolar electrode (see picture; inset: photograph of the film).

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