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Iron‐Catalyzed Oxidative Addition of Alkoxycarbonyl Radicals to Alkenes with Carbazates and Air
Author(s) -
Taniguchi Tsuyoshi,
Sugiura Yuki,
Zaimoku Hisaaki,
Ishibashi Hiroyuki
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201005574
Subject(s) - radical , reagent , catalysis , chemistry , organic chemistry , alkyl , aryl , simple (philosophy) , combinatorial chemistry , philosophy , epistemology
Clean and simple : Alkoxycarbonyl radicals generated from carbazates by iron catalysis in air underwent addition to a variety of alkenes to give the corresponding β‐hydroxyesters (see scheme). The simple experimental procedure for this transformation has the added advantage that the reagents are environmentally friendly. R 1 ,R 2 =alkyl, alkynyl, aryl, CO 2 Et; [Fe(Pc)]=iron phthalocyanine.