Iron‐Catalyzed Oxidative Addition of Alkoxycarbonyl Radicals to Alkenes with Carbazates and Air | Zendy

Taniguchi Tsuyoshi | Zendy; Sugiura Yuki | Zendy; Zaimoku Hisaaki | Zendy; Ishibashi Hiroyuki | Zendy

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Iron‐Catalyzed Oxidative Addition of Alkoxycarbonyl Radicals to Alkenes with Carbazates and Air

Author(s) -

Taniguchi Tsuyoshi,

Sugiura Yuki,

Zaimoku Hisaaki,

Ishibashi Hiroyuki

Publication year - 2010

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.201005574

Subject(s) - radical , reagent , catalysis , chemistry , organic chemistry , alkyl , aryl , simple (philosophy) , combinatorial chemistry , philosophy , epistemology

Clean and simple : Alkoxycarbonyl radicals generated from carbazates by iron catalysis in air underwent addition to a variety of alkenes to give the corresponding β‐hydroxyesters (see scheme). The simple experimental procedure for this transformation has the added advantage that the reagents are environmentally friendly. R 1 ,R 2 =alkyl, alkynyl, aryl, CO 2 Et; [Fe(Pc)]=iron phthalocyanine.

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