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Rapid Room‐Temperature Synthesis of Zeolitic Imidazolate Frameworks by Using Mechanochemistry
Author(s) -
Beldon Patrick J.,
Fábián László,
Stein Robin S.,
Thirumurugan A.,
Cheetham Anthony K.,
Friščić Tomislav
Publication year - 2010
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201005547
Subject(s) - zeolitic imidazolate framework , imidazolate , grinding , mechanochemistry , nanotechnology , zinc , materials science , porous medium , porosity , chemistry , metal organic framework , inorganic chemistry , metallurgy , organic chemistry , adsorption , composite material
Freshly ground : Improved mechanochemical methodologies, such as liquid‐assisted grinding and ion‐ and liquid‐assisted grinding enable the rapid and topologically selective synthesis of porous and nonporous zeolitic imidazolate frameworks with diverse topologies, at room temperature and directly from zinc oxide (see scheme).