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Carbon–Sulfur Reductive Elimination from Palladium(IV) Sulfinate Complexes
Author(s) -
Zhao Xiaodan,
Dong Vy M.
Publication year - 2011
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.201005489
Subject(s) - palladium , reductive elimination , sulfur , chemistry , medicinal chemistry , organic chemistry , catalysis
Sulfurin succotash : The oxidation of Pd II complexes with sulfonyl chlorides leads to a series of stable palladium(IV) sulfinate complexes. These complexes undergo reductive elimination to afford products with CS, CC, and CCl bonds, as well as a desulfitated product (see scheme; Py=pyridyl, Pd gray, N blue, S yellow, O red).
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